A novel block copolymer containing gadolinium oxide nanoparticles in ultrasound assisted-dispersive solid phase microextraction of total arsenic in human foodstuffs: A multivariate optimization methodology
Jamshed Ali, Mustafa Tuzen, Wahid Bux Jatoi, B Hazer
article (Uluslararası, Hakemli) | Yazar(lar): Jamshed Ali, Mustafa Tuzen, Wahid Bux Jatoi, B Hazer | Yıl: 2024 | Dergi/Kurum: FOOD CHEMISTRY | İndeks: WOS.SCI | DOI: 10.1016/j.foodchem.2023.137908 | Anahtar Kelimeler: Total arsenic, Foodstuffs, PHB-PDMAEMA, Gd2O3-NPs, UA-dSP mu E, HG-AAS — Özet: A new poly(3-hydroxy bu
A new poly(3-hydroxy butyrate)-b-poly(dimethyl amino ethyl methacrylate) amphiphilic block copolymer containing gadolinium oxide nanoparticles (PHB-PDMAEMA-Gd2O3-NPs) were synthesized and used as composite adsorbent for extraction of total arsenic. Characterization of the composite adsorbent material PHB-PDMAEMA-Gd2O3-NP was studied using spectroscopic techniques. Plackett-Burman design and central composite design were employed to screening and optimization of the experimental parameters. This composite adsorbent was utilized in ultrasound assisted-dispersive solid phase microextraction (UA-dSP mu E) for the determination of total inorganic arsenic in foodstuffs through hydride generation atomic absorption spectrometry (HG-AAS). It demonstrates a linear relationship across arsenic concentration range of 0.07-1.12 mu g/L with a correlation coefficient (0.996). It's showed an enrichment factor of 128 and a limit of detection 0.02 mu g/L for total inorganic arsenic determination. Accuracy of the developed method was confirmed through the analysis of certified reference materials with 96.0-98.5% recovery. It proved to be significantly useful UA-dSP mu E method for determining total inorganic arsenic in different foodstuffs.