Synthesis of Segmented Polyurethane Based on Polymeric Soybean Oil Polyol and Poly (Ethylene Glycol)
Elif Keles, B Hazer
article (Uluslararası, Hakemli) | Yazar(lar): Elif Keles, B Hazer | Yıl: 2009 | Dergi/Kurum: JOURNAL OF POLYMERS AND THE ENVIRONMENT | İndeks: WOS.SCI | DOI: 10.1007/s10924-009-0132-0 | Anahtar Kelimeler: Soybean oil, Polyurethane, Autoxidation — Özet: Polyurethane (PUR) plastic sheets were prepared by reacting hydroxy
Polyurethane (PUR) plastic sheets were prepared by reacting hydroxylated polymeric soybean oil (PSbOH) synthesized from autoxidized soybean oil with polyethylene glycol (PEG) in the presence of isophorone diisocyanate (IPDI). FTIR technique was used to identify of chemical reactions. These polyurethanes have different valuable properties, determined by their chemical composition. The effect of stoichiometric balance (i.e., PSbOH/PEG-2000/IPDI weight ratio) on the final properties was evaluated. The polyurethane plastic sheets with the PSbOH/PEG-2000/IPDI weight ratio 1.0/1.0/0.67 and 1.0/0.3/0.3 had excellent mechanical properties indicating elongation at break more than 200%. Increase in IPDI and decrease in PEG weight ratio cause the higher stress-strain value. The properties of the materials were measured by differential scanning calorimetry (DSC), thermo gravimetric analysis (TGA), stress-strain measurements and FTIR technique.