Allyl complexes of molybdenum with Schiff base ligands.: The crystal structures of [MoCl(CO)<sub>2</sub>{N(C<sub>6</sub>H<sub>4</sub>-2-OMe)=C(Me)C<sub>5</sub>H<sub>4</sub>N}(η<SUP>3</SUP>-C<sub>3</sub>H<sub>5</sub>)] and [MoCl(CO)<sub>2</sub>{N(Me)=C(Ph)C<sub>5</sub>H<sub>4</sub>N}(η<SUP>3</SUP>-C<sub>3</sub>H<sub>5</sub>)] are described
A Mentes, RDW Kemmitt, J Fawcett, DR Russell
article (Uluslararası, Hakemli) | Yazar(lar): A Mentes, RDW Kemmitt, J Fawcett, DR Russell | Yıl: 2002 | Dergi/Kurum: JOURNAL OF ORGANOMETALLIC CHEMISTRY | İndeks: WOS.SCI | Anahtar Kelimeler: allyl, carbonyl, molybdenum, pyridyl amine, Schiff base, X-ray structure — Özet: Treatment of the molybdenum tetracarbonyl comp
Treatment of the molybdenum tetracarbonyl complexes Of [Mo(CO)(4)L-2] (L-2 = pyridyl amine Schiff base ligands) with allyl chloride in refluxing THF afforded eta(3)-allyl complexes [MoCl(CO)(2)L-2(eta(3)-allyl)] (1-9). These complexes have been characterised by various techniques including H-1-NMR, IR and FABMS spectroscopies and the single crystal X-ray structure determinations of the Complexes [MoCl(CO)(2){N(C6H4-2-OMe)=C(Me)C5H4N}(eta(3)-C3H5)] (3) and [MoCl(CO)(2){N(Me)=C(Ph)C5H4N}(eta(3)-C3H5)] (4). (C) 2002 Elsevier Science B.V. All rights reserved.