Synthesis and crystal structure of diaquatetra(5-methyl-1,2-oxazol-3-amine)iron(II) perchlorate
Y Baran, W Linert
article (Uluslararası, Hakemli) | Yazar(lar): Y Baran, W Linert | Yıl: 2001 | Dergi/Kurum: JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | İndeks: WOS.SCI | Anahtar Kelimeler: Fe(II), oxazol derivatives, susceptibility — Özet: A new monomeric iron(II) complex of 5-methyl-1,2-oxazol-3-amine(moxa) has been synthesized and structur
A new monomeric iron(II) complex of 5-methyl-1,2-oxazol-3-amine(moxa) has been synthesized and structurally characterized. Fe(II) atom is in a distorted octahedral environment with four ring N atoms of the oxazol and two water ligands. Complex molecules and uncoordinated oxazol ligands are linked together by hydrogen bonding. This complex is diamagnetic at different temperatures and no spin-crossover was observed. Magnetic susceptibility measurement was performed by Evans method in solution. IR and UV-vis spectrum of the complex was measured to investigate the solution behavior of the complex. The space group is P ($) over bar 1 (No. 2), with a = 7.4137(2), b = 10.9395(3), c = 13.5284(3) Angstrom, alpha = 67.146(1), beta = 88.565(1), gamma = 78.556(1)degrees, V = 989.31(4) Angstrom(3), and Z = 1.