Hexa(1-vinylimidazole)Co(II) perchlorate
W Linert, Y Barau
article (Uluslararası, Hakemli) | Yazar(lar): W Linert, Y Barau | Yıl: 1999 | Dergi/Kurum: JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | İndeks: WOS.SCI | Anahtar Kelimeler: d-block metals, imidazole derivatives, copper(II) — Özet: A new cobalt(II) complex of 1-vinylimidazole (vinim) has been synthesized as the perchlorate sal
A new cobalt(II) complex of 1-vinylimidazole (vinim) has been synthesized as the perchlorate salt and structurally characterized. The molecular structure of the complex exhibits six coordination in which the geomety is a distorted octahedron. The vinylimidazole ring is coordinated through the imidazole nitrogen, as expected from earlier spectroscopic studies of related adducts. The space group is P2(1)/n, with a = 8.512(2), b = 13.857(2), c = 16.146(2) Angstrom, beta = 96.30(1)degrees, V = 989.31 Angstrom(3), and Z = 2.