Metal ion exchange in dinuclear macrocyclic complexes identified by electrospray mass spectrometry
GA Lawrance, None None, Y Baran, EI von Nagy-Felsobuki, DT Richens, H Xiao
article (Uluslararası, Hakemli) | Yazar(lar): GA Lawrance, None None, Y Baran, EI von Nagy-Felsobuki, DT Richens, H Xiao | Yıl: 1999 | Dergi/Kurum: INORGANIC CHEMISTRY COMMUNICATIONS | İndeks: WOS.SCI | Anahtar Kelimeler: electrospray mass spectrometry, dinuclear complexes, copper(I) complexes, macrocyclic complexes, m
Dicopper(I) complexes of a two-compartment 34-membered bis-dithiadiimine macrocycle (1) in solution in the presence of silver(I) ion display in electrospray mass spectrometry experiments the presence of AgCu(1)(2+) and Ag-2(1)(2+) in addition to the original Cu-2(1)(2+), consistent with metal ion exchange in this helical complex occurring without fragmentation. (C) 1999 Elsevier Science S.A. All rights reserved.